Gunpowder, also known as black powder, is the earliest known chemical explosive. It is a mixture of sulfur, charcoal, and potassium nitrate (saltpeter). The sulfur and charcoal act as fuels, and the saltpeter is an oxidizer.   Because of its burning properties and the amount of heat and gas volume that it generates, gunpowder has been widely used as a propellant in firearms and as a pyrotechnic composition in fireworks. Formulations used in blasting rock (such as in quarrying) are called blasting powder.

Gunpowder is Combustible and is an Explosion Hazard:

When most people think of controlling dust in the workplace, they think of taking steps to avoid inhaling dusts to prevent health problems. However, the accumulation of combustible dusts in the workplace can lead to far greater consequences. As seen in recent years, neglect of housekeeping and improper handling of combustible dusts can lead to property damage, injuries and loss of life.

Nitrates have the property to release oxygen when heated, and this oxygen leads to the fast burning of carbon and sulfur, resulting in an explosion-like chemical reaction when gunpowder is ignited. The burning of carbon consumes oxygen and produces heat, which produces even more oxygen, etc. The presence of nitrates is crucial to gunpowder composition because the oxygen released from the nitrates exposed to heat makes the burning of carbon and sulfur so much faster that it results in an explosive action, although mild enough not to destroy the barrels of the firearms.

The National Fire Protection Association (NFPA) defines a combustible dust as “a combustible particulate solid that presents a fire or deflagration hazard when suspended in air or some other oxidizing medium over a range of concentrations, regardless of particle size or shape.”

In general, combustible particulates having an effective diameter of 420 μm or smaller, as determined by passing through a U.S. No. 40 Standard Sieve, are generally considered to be combustible dusts. However, agglomerates of combustible materials that have lengths that are large compared to their diameter (and will not usually pass through a 420 μm sieve) can still pose a deflagration hazard. Therefore, any particle that has a surface area to volume ratio greater than that of a 420 μm diameter sphere should also be considered a combustible dust. The vast majority of natural and synthetic organic materials, as well as some metals, can form combustible dust. The NFPA’s Industrial Fire Hazards Handbook states, “any industrial process that reduces a combustible material and some normally non-combustible materials to a finely divided state presents a potential for a serious fire or explosion.”

Suggested Industrial Vacuums for Recovery of Toxic & Combustible Dust

PrestiVac HEPAPlus* Vacuums are specifically designed to safely vacuum toxic dusts. Equipped with a Certified Absolute HEPAPlus*filter with an efficiency of 99.995% on 0.2 micron so there is no risk of exposure or contamination for the operator or the environment. These vacuums are tested for absolute filtration. Testing Method: IEST RP-CC034.3. H14. MIL-STD 282 / A.S.T.M. - D2986-91.  MPPS method EN 1822.

PrestiVac Explosion Proof/Dust Ignition Protected Vacuums are designed to safely vacuum explosive, flammable, combustible conductive* dusts. Our Explosion Proof/Dust Ignition Protected Vacuums are completely grounded and static dissipating because they are built entirely with non-sparking metals and do not have any painted components so there is no risk of fire or explosion from a spark or static build up. All the electrical components, including the motor and starter are totally enclosed so there is no source of ignition. Our explosion proof vacuum cleaners comply with NFPA 484 guidelines and are an effective tool for good housekeeping practise as per OSHA.

Which Industries are at Risk with Gunpowder?